Electric Literature of 10343-06-3, An article , which mentions 10343-06-3, molecular formula is C14H20O10. The compound – 2,3,4,6-Tetra-o-acetyl-D-glucopyranose played an important role in people’s production and life.
Asymmetric synthesis of (5S)-4-deoxy-5-C-(4-nitrophenyl)-L-threo-pentose and (5R)-5-C-(4-nitrophenyl)-L-arabinose
In the presence of Eu(fod)3, (1E)-(2′,3′,4′,6′-tetra-O-acetyl-I2-D-glucopyranosyloxy)buta-1,3-diene and its (3Z)-4-O-acetyl derivative undergo Re-face and endo selective hereto Diels-Alder reactions with 4-nitrobenzaldehyde, 5-nitrofuran-2-carbaldehyde and 5-nitrothiophene-2-carbaldehyde. The cycloadducts are converted into the title compounds, early examples of ‘free’ 5-C-arylpentopyranoses.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics