Synthetic Route of 499-40-1. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal. In a document type is Article, introducing its new discovery.
Metal Complexes with Sulphur Donor Ligands. Part-IV. Some Mixed Xanthate Complexes of Nickel(II) with N-Donor Ligands
Some new mixed ligand complexes of nickel(II) having the compositions Ni(RXan)2, Ni(RXan)2L2 and Ni(RXan)2L’, where RXan = 2-methoxyethylxanthate and 2-ethoxyethylxanthate; L = pyridine, beta-picoline, gamma-picoline, 3,5-lutidine, 3,5-dichloropyridine or isoquinoline; and L’ = 1,10-phenanthroline, 2,2′-iminodipyridine or 2,2′-dipyridyl have been synthesised and characterised on the basis of elemental analysis, magnetic susceptibility,infrared and electronic spectral studies.The free base complexes are diamagnetic, while the base adducts and the tris(xanthato) complexes are paramagnetic with distorted octahedral structures.Relevant ligand field parameters have been calculated for the six-coordinated complexes.
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Reference£º
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics