Synthetic Route of 499-40-1, As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves. An article , which mentions 499-40-1, molecular formula is C12H22O11. The compound – (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal played an important role in people’s production and life.
A series of gold(I) complexes [Au(PPh3)L]ClO4 (L = pyridine 1a, 2,6-dimethylpyridine 1b, 2,6-di-tert-butylpyridine 1c, quinoline 1d, acridine 1e, benzo[h]quinoline 1f, naphthyridine 2a, 1,10-phenanthroline 2b, 2,2?-biquinoline 2c, di-2-pyridyl ketone 2d, di-2-pyridylamine 3a or 2-(2-pyridyl)benzimidazole 3b) were prepared by reaction of L with [Au(PPh3)(ClO4)] which was synthesized in situ. All complexes were characterized by IR, UV/VIS and 1H NMR spectroscopy. The crystal and molecular structures of 1b, 2a and 3b were investigated by single-crystal X-ray diffraction techniques. The gold(I) is co-ordinated to one nitrogen atom and one phosphine atom. Detailed 1H NMR studies suggested that linear two-co-ordinated structures persist in solution and further that all the complexes [Au(PPh3)L]ClO4, (2a-2d), are fluxional species in which the co-ordination site of gold(I) rapidly exchanges between two nitrogen atoms of the ligand.
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Reference：
Tetrahydropyran – Wikipedia,
Tetrahydropyran – an overview | ScienceDirect Topics