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The copper(II) complexes with the third-generation quinolone gatifloxacin (Hgati) were prepared in the absence or presence of the N,N?-donor heterocyclic ligands 2,2?-bipyridylamine (bipyam), 1,10-phenanthroline (phen) or 2,2?-bipyridine (bipy) and were characterized physicochemically and spectroscopically. The crystal structures of complexes [Cu(gati)(bipyam)Cl]¡¤MeOH¡¤H2O and [Cu(MOM-gati)(bipy)Cl]¡¤MeOH¡¤3H2O (MOM?=?methoxymethyl) were determined by X-ray crystallography. The antimicrobial activity of the compounds was tested against four different microorganisms (Escherichia coli, Xanthomonas campestris, Staphylococcus aureus and Bacillus subtilis) and was found similar or higher than that of free Hgati. The interaction of the complexes with calf-thymus DNA was monitored by UV?vis spectroscopy and DNA-viscosity measurements and by competitive studies with ethidium bromide; intercalation is suggested as the most possible binding mode. The interaction of the complexes with human or bovine serum albumins was studied by fluorescence emission spectroscopy and the corresponding albumin-binding constants of the complexes were calculated.

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Tetrahydropyran – Wikipedia,
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(Chemical Equation Presented) Scaling down the activity: An efficient recyclable palladium-based catalyst has been developed for the aerobic oxidation of alcohols (see scheme). The combination of a substituted bipyridyl ligand and ordered mesoporous channels (in SBA) causes a synergistic effect that results in enhanced activity, the prevention of agglomeration of the palladium nanoparticles, and the generation of a durable catalyst.

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Tetrahydropyran – Wikipedia,
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The water-coordinated Sn atom in the centrosymmetric title compound, (C10H10N3)2[Sn2(C 7H2NO5)2-(C4H 9)4(H2O)2].2H2O, is seven-coordinate in a trans-C2SnNO4 pentagonal-bipyramidal geometry [C-Sn-C 156.6(1)]. The dianion is linked to two planar 2,2?-iminodipyridinium(1+) cations through the lattice water molecules via the amino bridges [Owater…Namino 2.810(5), Owater…Ohydroxy 2.633(4) and Owater…Ocarbonyl 2.927 (5) A]. A weaker water-water interaction connects the ion pair into a linear helical chain.

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Nitrato and isothiocyanato 2,2?-dipyridylamine (HDPA) complexes of La(III), Ce(III), Pr(III), Th(IV) and UO2(VI) have been synthesized An acetato complex of UO2(VI) is also reported in addition to a peroxo complex of UO2(VI) The complexes have been characterized by elemental analyses, molar conductances, magnetic measurements, UV-Vis, IR and thermogravimetric methods The lanthanide nitrato complexes are 1:1 electrolytes, chelated nitrato and ionic nitrate were established by IR measurements The ambidentate thiocyanate binds through the hard donor N-site The values of the bond stretching force constant (FU=0) and bond length (RU=0) of the uranyl complexes have been calculated The peroxo content was determined by redox titration and the compound was found to be thermally stable.

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The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.499-40-1, Name is (2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal, molecular formula is C12H22O11. In a Article£¬once mentioned of 499-40-1, category: Tetrahydropyrans

The syntheses and structures of copper(II) and cobalt(II) complexes employing tetraacetylethane as the bridging ligand have been investigated. The reaction of Cu(O2CCF3)2 with tetraacetylethane (tae) and 2,2?-dipyridylamine (dpa) yielded a dinuclear complex CuII2(dpa)2(tae)(O2CCF 3)2 (1), which has an extended hydrogen-bonded chain structure in the solid state. The reaction of 4,4?-dipyridyl (4,4?-bipy) with compound 1 resulted in the formation of a polymeric compound {[CuII2(dpa)2(tae)(4,4?-bipy)](O 2CCF3)2}n (2), where the dinuclear unit is crosslinked by the 4,4?-dipyridyl ligand. The reaction of Co(O2CCH3)2 with tetraacetylethane and 2,2?-dipyridylamine yielded a helical dinuclear complex [CoII2(dpa)4(tae)](O2CCH 3)2(H2O)2 (3), which forms a hydrogen-bonded band architecture in the solid state. The three-dimensional structure of 3 has molecular sieve-like channels that host methanol molecules reversibly. While only either negligible or weak magnetic exchanges appear to be present in compounds 1 and 2, there appears to be a significant ferromagnetic exchange in 3, which is likely caused by orbital orthogonality of the Co(II) ions, as supported by the crystal structure and EHMO calculations.

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The controlled crystallization of specific tantalum oxide-fluoride and tantalum fluoride anions ([TaOF5]2-, [TaF 6]-, and [TaF7]2-) is demonstrated using organic reagents with varied corresponding pKa values in the presence of aqueous hydrofluoric acid. The identity of tantalum oxide-fluoride or fluoride anions of [TaOF5]2-, [TaF6] -, and [TaF7]2- are shown to crystallize successively from solution to solid state by increasing the corresponding pKa of organic reagents, which lead to the subsequent increase of fluoride concentration in the hydrofluoric acid solution. With the use of this methodology, three new hybrid crystal structures were targeted: [H 2(2,2?-bpy)]TaOF5 (2,2?-bpy = 2,2?-bipyridyl) 1, [Hdpa]TaF6 (dpa = 2,2?-dipyridylamine) 2, and [H2En]TaF7 (En = ethylenediamine) 3, respectively. The applicability and comparison of this methodology for tantalum and previously prepared niobium compounds show that it can be broadly used to design new materials with specific functionalities for other transition metal oxide-fluorides.

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A new fluorescent chemosensor 5-(p-N,N?-bis(2-pyridyl)amino)phenyl-10,15,20-tris(p-methoxyphenyl)porphyrin zinc has been designed and synthesized by the Ullmann-type coupling. It displays high selectivity for Cu2+ ion and exhibits fluorescence quenching upon binding of Cu2+ ion with an “on-off” type fluoroionophoric switching property, and its fluorescence can be revived by addition of EDTA disodium solution.

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Cobalt(II) complexes with a series of non-steroidal anti-inflammatory drugs (diflunisal, flufenamic acid, mefenamic acid and niflumic acid) in the presence of nitrogen-(2,2?-bipyridylamine, 2,2?-bipyridine, 1,10-phenanthroline) and/or oxygen-donor ligands (methanol) have been synthesized and characterized with physicochemical and spectroscopic techniques. The deprotonated NSAID ligands are coordinated to Co(II) ion through their carboxylato groups in diverse binding modes. The crystal structures of complexes [Co(diflunisal-O)2(methanol)4], [Co(niflumato-O)2(methanol)4], [Co(flufenamato-O,O’)2(2,2?-bipyridylamine)], [Co(mefenamato-O,O’)2(2,2?-bipyridylamine)] and [Co3(flufenamato-O,O’)4(flufenamato-O,O,O’)2(2,2?-bipyridine)2] have been determined by X-ray crystallography. The interaction of the complexes with serum albumins was studied by fluorescence emission spectroscopy and the albumin-binding constants were determined. The ability of the complexes to scavenge 1,1-diphenyl-picrylhydrazyl, 2,2?-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) and hydroxyl radicals was investigated and the complexes were more active than the corresponding free drugs. Spectroscopic (UV and fluorescence), electrochemical (cyclic voltammetry) and physicochemical (viscosity measurements) techniques were employed in order to study the binding mode of the complexes to calf-thymus (CT) DNA and to calculate the corresponding binding constants; for all complexes, intercalation was suggested as the most possible DNA-binding mode.

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A new redox polymer containing Os (E? = -0.15 V vs Ag|AgCl) was designed and synthesized as an efficient mediator of diaphorase-catalyzed electrochemical oxidation of NADH and as a support to immobilize enzyme(s) on electrode surfaces. The electrochemical characteristics of the polymer and its application to biosensors and bioanodes of biofuel cells are briefed.

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The hydrothermal reactions of V2O5, Cu(CH 3CO2)2¡¤H2O, an appropriate imine, a xylyl-diphosphonic acid and HF in low HF/V ratio yielded the bimetallic xylyldiphosphonate phases, [Cu(o-phen)VO2(1,2-HO3PC 8H8PO3)] (1) and [Cu2(dpa) 2V2O5(1,3-O3PC8H 8PO3)] (2). When the HF/V ratio was increased to ca. 23:1, a series of materials of the VxFyOz/copper- imine/xylyldiphosphonate family were prepared. These include the one-dimensional [Cu2(o-phen)2V2F2O 4(H2O)(1,3-O3PC8H8PO 3)] (3), the two-dimensional [Cu2(o-phen) 2V2F2O4(1,4-O3PC 8H8PO3)] (4), [Cu2(dpa) 2V2F2O4(1,2-O3PC 8H8PO3)] (5) and [Cu2(dpa) 2V2F2O4(1,3-O3PC 8H8PO3)] (6¡¤H2O), and the three-dimensional [Cu2(bpy)2V2F 2O4(1,4-O3PC8H8PO 3)] (7) and [{Cu2(tpyprz)(H2O) 2}V2F2O4(1,3-O3PC 8H8PO3)] (8¡¤2H2O). The influences of structural determinants such as the xylyldiphosphonate geometry, the identity of the imine coligand and fluoride substitution for oxide are discussed.

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Tetrahydropyran – Wikipedia,
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